INTERNAL ACTIVATION OF ACRYLATE-TYPE DIENOPHILES IN DIELS-ALDER REACTIONS

被引：14

作者：

KAN, T ^{[1
]}

OHFUNE, Y ^{[1
]}

机构：

[1] SUNTORY INST BIOORGAN RES,SHIMAMOTO,OSAKA 618,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 06期

关键词：

D O I：

10.1016/0040-4039(94)02379-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diels-Alder reactions of less reactive acrylate-type dienophiles with dienes were achieved by replacing its ester counterpart to a pentafluorophenyl group, which remarkably enhanced the reactivity of the dienophiles to give the corresponding cycloadducts in excellent yields with a high stereoselectivity.

引用

页码：943 / 946

页数：4

共 6 条

[1] TOTAL SYNTHESIS OF (-)-GRAYANOTOXIN-III [J].