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THE PROBABILITY OF NONADIABATIC ELECTRON-TRANSFER AS A FUNCTION OF FRICTION

被引：18
作者：
BURSHTEIN, AI
ZHARIKOV, AA
机构：
[1] Institute of Chemical Kinetics and Combustion, Siberian Branch, The USSR Academy of Sciences
来源：
CHEMICAL PHYSICS | 1991年 / 152卷 / 1-2期
关键词：
D O I：
10.1016/0301-0104(91)80031-C
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The probability of non-adiabatic electron transfer is calculated as a function of friction. With the increase of friction, the process speeds up in the beginning and afterwards it slows down. It is shown, that this result peculiar for weak (non-adiabatic) intercenter interaction, essentially differs from its strong (adiabatic) analogue which was first described by Kramers.
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页码：23 / 30
页数：8
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