INTERDEPENDENT SITE EXCHANGE PROCESS OF SOME 16-ELECTRON BIS-ACETYLENE-MOLYBDENUM COMPLEXES

被引：35

作者：

FALLER, JW

MURRAY, HH

机构：

[1] Department of Chemistry, Yale University, New Haven

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 172卷 / 02期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/S0022-328X(00)81044-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The propeller-like rotations of each of the coordinated acetylenes in the 16-electron complex (η5-C5H5)Mo(PhCCMe)2Cl are not independent and the barrier to rotation of one of the acetylenes is influenced by the orientation of the other. The barrier for the propeller-like rotation of the coordinated acetylenes in the similar cationic bis-acetylene complex, [(η5-C5H5)Mo(HOH2CCCCH2OH)2CO]Cl is >5 kcal/mol higher than in the neutral bis-acetylene (η5-C5H5)Mo(PhCCCH3)2Cl. © 1979.

引用

页码：171 / 176

页数：6

共 7 条

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[6] The measurement of the conductance of electrolytes V. A redetermination of the conductance of standard potassium chloride solutions in absolute units
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