MILLIMETER WAVELENGTH SPECTRUM OF DIATOMIC SULFUR

被引：22

作者：

PICKETT, HM ^{[1
]}

BOYD, TL ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1979年 / 75卷 / 01期

关键词：

D O I：

10.1016/0022-2852(79)90145-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The gas phase spectrum of diatomic sulfur has been detected in the millimeter wave-length region. Six lines have been measured. The rotational and fine structure parameters obtained are B0 = 8831.8676 ± 0.006 MHz, D0 = 5.9 ± 0.7 kHz, λ0 = 353040 ± 27 MHz, and γ0 = - 200.9 ± 0.7 MHz. In addition, reanalysis of EPR data has yielded gz + 1.18gn = 2.0021 + 0.0014 and gz - g⊥ = -0.0089 ± 0.0017. On the basis of the frequencies obtained in this work, it was also possible to exclude the assignment of several interstellar emissions to the sulfur dimer. © 1979.

引用

页码：53 / 57

页数：5