THE FIRST SECO-ASBESTININ - A NOVEL CLASS OF DITERPENE FROM THE CARIBBEAN GORGONIAN BRIAREUM-ASBESTINUM (PALLAS)

被引：17

作者：

RODRIGUEZ, AD

COBAR, OM

MARTINEZ, N

机构：

[1] Department of Chemistry, University of Puerto Rico, Puerto Rico, 00931-3346, P.O. Box 23346, U.P.R. Stn. San Juan

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 32期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)78186-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The hexane extract of the Caribbean gorgonian octocoral Briareum asbestinum was found to contain traces of a novel seco-asbestinin diterpenoid. The structure of 1, the first representative of this novel class of diterpenoids, was assigned on the basis of extensive NMR analyses and by comparison with analogous spectral data from related asbestinane diterpenoids. Confirmation of structure 1 was achieved by partial synthesis from known asbestinin-6 (2).

引用

页码：5793 / 5796

页数：4

共 4 条

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MORALES, JJ ;

LORENZO, D ;

RODRIGUEZ, AD .

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[2] 2-DIMENSIONAL NMR-SPECTRA OF ASBESTININ DITERPENES ISOLATED FROM BRIAREUM-ASBESTINUM (PALLAS) - TOTAL STEREOCHEMICAL ASSIGNMENT BY 2-DIMENSIONAL NMR TECHNIQUES [J].

RODRIGUEZ, AD .

MAGNETIC RESONANCE IN CHEMISTRY, 1992, 30 (10) :977-986

[3] STRUCTURES AND BIOACTIVITIES OF NEW ASBESTININ DITERPENOIDS FROM THE CARIBBEAN GORGONIAN OCTOCORAL BRIAREUM-ASBESTINUM [J].

RODRIGUEZ, AD ;

COBAR, OM .

TETRAHEDRON, 1993, 49 (02) :319-328

[4] THE ASBESTININS, A NOVEL CLASS OF DITERPENES FROM THE GORGONIAN BRIAREUM-ASBESTINUM [J].

STIERLE, DB ;

CARTE, B ;

FAULKNER, DJ ;

TAGLE, B ;

CLARDY, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (15) :5088-5092

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