CHARACTERIZATION OF HYDRIDOPALLADIUM COMPLEXES

被引：14

作者：

HEATON, BT ^{[1
]}

HEBERT, SPA ^{[1
]}

IGGO, JA ^{[1
]}

METZ, F ^{[1
]}

WHYMAN, R ^{[1
]}

机构：

[1] RHONE POULENE RECH,CTR RECH CARRIERES,F-69192 ST FONS,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 20期

关键词：

D O I：

10.1039/dt9930003081

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydride complexes trans-[PdH(X)(PPh3)2]] (X = Cl or Br) have been prepared in good yield by hydrogenolysis of trans-[PdX(COPh)(PPh3)2] or trans-[PdXPh(PPh3)2]. They have been fully characterised by NMR and IR spectroscopic measurements and shown to have the trans configuration. The mechanism of the hydrogenolysis reaction and the role of these hydride species in catalytic reactions are discussed.

引用

页码：3081 / 3084

页数：4

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