RAPID, LOW-ENERGY SYNTHESIS OF LANTHANIDE NITRIDES

被引：49

作者：

FITZMAURICE, JC ^{[1
]}

HECTOR, A ^{[1
]}

ROWLEY, AT ^{[1
]}

PARKIN, IP ^{[1
]}

机构：

[1] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND

来源：

POLYHEDRON | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)86597-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal initiation (400 degrees C) of the reaction between lithium nitride and anhydrous lanthanide halides produces lanthanide nitrides LnN (Ln = Y, La, Pr, Nd, Sm, Eu, Cd, Tb, Dy, Ho, Er, Yb) via a rapid exothermic solid state metathesis reaction. Mixed lanthanide nitrides LnLn'N (LnLn' = PrNd; DyHo; TbDy) are made by reaction of ground powders of LnCl(3) with Li3N. The lanthanide nitrides were characterized by X-ray powder diffraction, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA), FTIR, magnetic moment measurement and microanalysis.

引用

页码：235 / 240

页数：6

共 20 条

[1] Bailar J.C., 1975, COMPREHENSIVE INORGA
[2] BANASZAK MM, 1990, INORG CHEM, V29, P1518
[3] SOLID-STATE METATHESIS AS A QUICK ROUTE TO TRANSITION-METAL MIXED DICHALCOGENIDES
BONNEAU, PR
JARVIS, RF
KANER, RB
[J]. INORGANIC CHEMISTRY, 1992, 31 (11) : 2127 - 2132
[4] BROWN BR, 1964, MELLORS COMPREHEN S1, V8, P153
[5] DUCA RL, 1992, INORG CHEM, V31, P1311
[6] SOLUTION-PHASE REACTIVITY AS A GUIDE TO THE LOW-TEMPERATURE CHEMICAL VAPOR-DEPOSITION OF EARLY-TRANSITION-METAL NITRIDE THIN-FILMS
FIX, RM
GORDON, RG
HOFFMAN, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (21) : 7833 - 7835
[7] FLAHAUT J, 1968, PROGR SCI TECHNOLOGY, V3, P176
[8] Hulliger F., 1979, Handbook on the physics and chemistry of rare-earths, vol. 4. Non-metallic compounds II, P153, DOI 10.1016/S0168-1273(79)04006-X
[9] JOHNSON HA, 1977, SURV PROGR CHEM, P57
[10] KANER RB, 1991, NATURE, V349, P519

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