[CIS-PT(C6F5)(2)(C-CPH)(2)](2-) AS A DOUBLE ALKYNYL TRANSFER REAGENT, SYNTHESIS AND CHARACTERIZATION OF THE IR(III)-PT(II) TWEEZER COMPLEX ([(ETA(5)-C(5)ME(5))(PET(3))IR(C-CPH)(2)]PT(C6F5)(2))

被引：28

作者：

BERENGUER, JR

FORNIES, J

LALINDE, E

MARTINEZ, F

机构：

[1] UNIV ZARAGOZA, CSIC, INST CIENCIA MAT ARAGON, DEPT QUIM INORGAN, E-50009 ZARAGOZA, SPAIN

[2] UNIV LA RIOJA, DEPT QUIM, E-26001 LOGRONO, SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 12期

关键词：

D O I：

10.1039/c39950001227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[cis-Pt(C6F5)(2)(C=CPh)(2)](2-) reacts with [Ir(C(5)Me(5))(PEt(3))(Me(2)CO)(2)](ClO4)(2), via a double alkynylation process, yielding {[(eta(5)-C(5)Me(5))(PEt(3))Ir(C=CPh)(2)]Pt(C6F5)(2)} in which the alkynyl groups are sigma bonded to the iridium centre and pi bonded to the platinum one.

引用

页码：1227 / 1228

页数：2

共 22 条

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