STUDIES OF DIAZO-COMPOUNDS AND AZIDES .34. (DIAZOMETHYL)CYCLOPROPENES - SYNTHESIS, ISOMERIZATION, AND CARBENE REACTIONS

被引：20

作者：

REGITZ, M

HEYDT, A

WEBER, B

机构：

[1] Fachbereich Chemie der Universität, Kaiserslautern, D-6750, Paul-Ehrlich-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1002/anie.197905312

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrophilic substitution of diazo compounds with cyclopropenylium and other Hückel‐aromatic cations affords products of versatile reactivity: e.g (1), R1 = R2 = Ph, isomerizes to the pyridazine 2; on irradiation 1 forms the carbene. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：531 / 533

页数：3

共 11 条

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[2] SUBSTITUTED CYCLOPROPENONES
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[6] PROPERTIES OF [4]ANNULENE SYSTEM - INDUCED PARAMAGNETIC RING CURRENT
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[7] REGITZ M, 1971, J LIEBIGS ANN CHEM, V748, P207
[8] REGITZ M, 1977, DIAZOALKANE, P235
[9] SOME REACTIONS OF DIMETHYLPHOSPHONO-SUBSTITUTED DIAZOALKANES - (MEO)2P(O)CR TRANSFER TO OLEFINS AND 1,3-DIPOLAR ADDITIONS OF (MEO)2P(O)C(N2)R
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[10] WEISE G, 1979, FORTGESCHRITTENENARB

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