A DIFFERENTIAL SCANNING CALORIMETRY STUDY OF A BINARY-SYSTEM .3. HEAT-CAPACITY OF THE LYOTROPIC LIQUID-CRYSTAL DIMETHYLDECYLPHOSPHINE OXIDE-WATER SYSTEM

被引：7

作者：

CHERNIK, GG

FILIPPOV, VK

机构：

[1] Leningrad State University, Department of Chemistry, University pr. 2, 198904 Leningrad, Petrodvorets

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1991年 / 141卷 / 02期

关键词：

D O I：

10.1016/0021-9797(91)90338-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Heat capacity data and heat capacity jumps at phase transitions in a dimethyldecylphosphine oxide-water system are reported. A three-dimensional diagram of the dependence of the heat capacity of the system on concentration and temperature (including heterogeneous regions) is presented. Differential entropy and enthalpy effects of dissolution of one phase in another are calculated using experimental data on heat capacity jumps or enthalpies of phase transitions. Ways of verifying the thermodynamic consistency of the data are considered. Possibilities of the differential scanning calorimetry (DSC) technique in the study of thermodynamic properties of binary systems are summarized. © 1991.

引用

页码：415 / 425

页数：11

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[3]

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[4]

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[5]

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[9]

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