PALLADIUM-CATALYZED CLEAVAGE OF PROCHIRAL ENOL CARBONATES - ENANTIOSELECTIVE KETONIZATION OF RESULTING ENOLS

被引:50
作者
HENIN, F
MUZART, J
机构
[1] Unité Réarrangements Thermiques, Photochimiques Associée au CNRS Université de Reims Champagne-Ardenne, 51062 Reims Cedex
关键词
D O I
10.1016/S0957-4166(00)82102-3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The palladium-catalyzed protection of (2-methyl-1-indenyl) benzyl carbonate and (2-methyl-1-indenyl) allyl carbonate in the presence of (+) or (-)ephedrine has led to 2-methyl-1-indanone ;with enantiomeric excesses of up to 40%.
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页码:1161 / 1164
页数:4
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