ELECTROCHEMICALLY INDUCED DEHYDROGENATION OF THE HYDRIDE COMPLEXES [RECLH(NCR)(PH2PCH2CH2PPH2)2][BF4] - A MECHANISTIC STUDY

被引：25

作者：

AMATORE, C ^{[1
]}

DASILVA, JJRF ^{[1
]}

DASILVA, MFCG ^{[1
]}

POMBEIRO, AJL ^{[1
]}

VERPEAUX, JN ^{[1
]}

机构：

[1] Univ Tecn Lisboa, CTR QUIM ESTRUTURAL, INST SUPER TECN, P-1096 LISBON, PORTUGAL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical behaviour of the hydride complexes [ReClH(NCR)(dppe)2][BF4] (R = Ph, 4-ClC6H4 or 4-FC6H4; dppe = Ph2PCH2CH2PPh2), prepared by protonation of the corresponding nitrile compounds [ReCl(NCR)(dppe)2], has been studied by cyclic voltammetry (CV) and controlled-potential electrolysis in aprotic media, at a Pt electrode; they undergo anodically induced deprotonation and cathodically induced dehydrogenation, the former involving an overall bimolecular process as indicated by CV simulation techniques.

引用

页码：1289 / 1291

页数：3

共 20 条

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