MICROCALORIMETRIC STUDIES OF ZEOLITE ACIDITY

被引:77
作者
CHEN, DT
SHARMA, SB
FILIMONOV, I
DUMESIC, JA
机构
[1] UNIV WISCONSIN,DEPT CHEM ENGN,1415 JOHNSON DR,MADISON,WI 53706
[2] MV LOMONOSOV STATE UNIV,DEPT CHEM,KINET & CATALYSIS LAB,MOSCOW 117234,USSR
关键词
ACIDITY; GRAVIMETRY; HEAT OF ADSORPTION; H-MORDENITE; H-Y; H-ZSM-5; MICROCALORIMETRY; PYRIDINE; ZEOLITE;
D O I
10.1007/BF00767202
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The acidity characteristics of H-ZSM-5, H-Mordenite and H-Y zeolite have been studied by microcalorimetric and gravimetric measurements of pyridine adsorption. H-ZSM-5 and H-Mordenite have Bronsted acid sites of primarily homogenous strength, with H-Mordenite having the stronger sites, whereas H-Y zeolite had Bronsted sites of varying strength. The effects of Na exchange level in H-Y zeolite and high temperature calcination for H-Mordenite have also been examined.
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页码:201 / 212
页数:12
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