PALLADIUM-CATALYZED CONSECUTIVE ONE-POT REACTION OF ACETYLENES WITH ALLYL BROMIDE AND ORGANOTIN COMPOUNDS

被引:23
作者
KOSUGI, M [1 ]
SAKAYA, T [1 ]
OGAWA, S [1 ]
MIGITA, T [1 ]
机构
[1] TOKAI UNIV, SCH HIGH TECHNOL HUMAN WELFARE, SHIZUOKA 41003, JAPAN
关键词
D O I
10.1246/bcsj.66.3058
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Allyl bromide adds to a terminal acetylene under the palladium complex to give 1-bromo-1,4-pentadiene which can further react with organotin compounds without further addition of palladium complex to give 1-substituted 1,4-pentadiene. These two reactions involving different catalytic species can be composed into the consecutive one-pot process.
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页码:3058 / 3061
页数:4
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