MICROWAVE SPECTROSCOPIC DETECTION OF BFHOH AND BH(OH)2

被引：29

作者：

KAWASHIMA, Y

TAKEO, H

MATSUMURA, C

机构：

[1] National Chemical Laboratory for Industry, Shibuya-ku, Tokyo, 151, Honmachi

来源：

CHEMICAL PHYSICS LETTERS | 1978年 / 57卷 / 01期

关键词：

D O I：

10.1016/0009-2614(78)80371-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transient molecules, BFHOH and BH(OH)2, have been detected by microwave spectroscopy in the hydrolyses of diborane and BF3. Their conformations have been determined from the inertia defects and the differences in moments of inertia between normal and deuterated species. © 1978.

引用

页码：145 / 147

页数：3

共 8 条

[1] COYLE TD, 1964, P CHEM SOC LONDON, P25
[2] MOLECULAR-ORBITAL THEORY OF ELECTRONIC-STRUCTURE OF ORGANIC COMPOUNDS .24. GEOMETRIES AND ENERGIES OF SMALL BORON-COMPOUNDS COMPARISONS WITH CARBOCATIONS
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[3] BARRIER TO INTERNAL-ROTATION AND PI-BONDING IN HYDROXYBORANE, H2BOH, STUDIED BY AB-INITIO CALCULATIONS
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[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (01) : 1 - &
[5] KAWASHIMA Y, UNPUBLISHED
[6] HEATS OF FORMATION OF GASEOUS H2BOH + HB(OH)2
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GUPTA, SK
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (09) : 2732 - &
[7] MICROWAVE-SPECTRUM OF BF2OH
TAKEO, H
CURL, RF
[J]. JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (09) : 4314 - &
[8] MECHANISM OF THE HYDROLYSIS OF DIBORANE IN THE VAPOR PHASE
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SHAPIRO, I
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (05) : 1221 - 1224

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