PHOTO-IONIZATION OF ETHYLENE CLUSTERS

被引：67

作者：

CEYER, ST ^{[1
]}

TIEDEMANN, PW ^{[1
]}

NG, CY ^{[1
]}

MAHAN, BH ^{[1
]}

LEE, YT ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 05期

关键词：

D O I：

10.1063/1.437758

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The energetics of the ethylene ion-molecule reactions has been investigated in more detail than previously possible in two body collision experiments by photoionization of the neutral van der Waals ethylene dimer. The stability of the ion-molecule collision complex (18.2±0.5 kcal) as well as the highest potential barrier along the reaction coordinate for decomposition have been determined for this exothermic reaction. In a similar manner, the energetics of the solvated ethylene ion has been investigated by photoionization of the ethylene trimer. © 1979 American Institute of Physics.

引用

页码：2138 / 2144

页数：7

共 36 条

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