SYNTHESIS AND STRUCTURE OF THE POLYCYCLOHEXAPHOSPHINES P6(C5ME5)4 AND P6(C5ME5)2

被引：21

作者：

JUTZI, P

KROOS, R

MULLER, A

BOGGE, H

PENK, M

机构：

[1] Fakultät für Chemie, Universität Bielefeld, Bielefeld, D-4800, Universitätsstraße

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 01期

关键词：

HEXAPHOSPHINES; POLYCYCLIC; BICYCLO[3.1.0]HEXAPHOSPHINE; TRICYCLO[3.1.0.02.6]HEXAPHOSPHINE;

D O I：

10.1002/cber.19911240112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cyclotriphosphine (PC5Me5)3 (1) decomposes in boiling benzene to give the bicyclo[3.1.0]hexaphosphine P6(C5Me5)4 (2) which yields the tricyclo[3.1.0.0(2.6)]hexaphosphine P6(C5Me5)2 (3) in boiling xylene. The structures of 2 and 3 have been determined by P-31-, C-13-, and H-1-NMR spectroscopy and by X-ray crystallography. 3 represents the first member of a new class of polyphosphines. The specific thermolysis of 1 and 2 under comparatively mild conditions is based on the easy homolytic cleavage of P-C5Me5 bonds in these compounds.

引用

页码：75 / 81

页数：7