TRANSPORT-PROPERTIES OF NONELECTROLYTE MIXTURES .9. VISCOSITY COEFFICIENTS FOR ACETONITRILE AND FOR 3 MIXTURES OF TOLUENE + ACETONITRILE FROM 25-DEGREES-C TO 100-DEGREES-C AT PRESSURES UP TO 500 MPA

被引:40
作者
DYMOND, JH [1 ]
AWAN, MA [1 ]
GLEN, NF [1 ]
ISDALE, JD [1 ]
机构
[1] NATL ENGN LAB,GLASGOW G75 0QU,SCOTLAND
关键词
ACETONITRILE; GRUNBERG AND NISSAN EQUATION; HIGH PRESSURE; TOLUENE; VISCOMETER; VISCOSITY;
D O I
10.1007/BF00502360
中图分类号
O414.1 [热力学];
学科分类号
摘要
A two-coil self-centering falling-body viscometer has been used to measure viscosity coefficients for acetonitrile and three binary mixtures of toluene + acetonitrile at 25, 50, 75, and 100-degrees-C and pressures up to 500 MPa. The results for acetonitrile can be interpreted by an approach based on hard-sphere theory, with a roughness factor of 1.46. The binary-mixture data are well represented by the Grunberg and Nissan equation with a mixing parameter which is pressure and temperature dependent but composition independent.
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页码:433 / 447
页数:15
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