MOLECULAR-STRUCTURE OF TETRACARBONYLHYDRIDO(1,1,4,4-TETRAPHENYL-1,4-DIPHOSPHABUTANE)VANADIUM(+I),HV(CO)4(PH2PCH2CH2PPH2)

被引：30

作者：

GREISER, T ^{[1
]}

PUTTFARCKEN, U ^{[1
]}

REHDER, D ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-2000 HAMBURG 13,FED REP GER

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 03期

关键词：

D O I：

10.1007/BF00619061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structures of the title compound have been determined. The compound crystallizes in the orthorhombic space group Pcab with a = 1463.3(30), b = 1663.1(36), c = 2250.1(47) pm and Z = 8. The molecular structure is best described as a distorted pentagonal bipyramid, the hydride ligand lying in a plane formed by vanadium, the two phosphorus atoms and two carbon monoxide groups. The V-H bond length is 155.2(93) pm, and the distance between H- and the nearest phosphorus atom is 157.9(118) pm. In solution, HV(CO)4Ph2P(CH2)2PPh2 appears to be fluxional. © 1979 Verlag Chemie, GmbH.

引用

页码：168 / 171

页数：4

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