ELECTRON-RESERVOIR COMPLEXES [FE(I)CP(ARENE)] AS SELECTIVE INITIATORS FOR A NOVEL ELECTRON-TRANSFER CHAIN CATALYZED REACTION - GENERAL-SYNTHESIS OF FULVALENE-BRIDGED HOMODINUCLEAR AND HETERODINUCLEAR ZWITTERIONS

被引：38

作者：

BROWN, DS

DELVILLEDESBOIS, MH

BOESE, R

VOLLHARDT, KPC

ASTRUC, D

机构：

[1] UNIV CALIF BERKELEY, DEPT CHEM, BERKELEY, CA 94720 USA

[2] UNIV CALIF BERKELEY, LAWRENCE BERKELEY LAB, DIV CHEM SCI, BERKELEY, CA 94720 USA

[3] UNIV BORDEAUX 1, CHIM ORGAN & ORGANOMET LAB, CNRS, URA 35, F-33405 TALENCE, FRANCE

[4] UNIV ESSEN GESAMTHSCH, INST ANORGAN CHEM, D-45117 ESSEN, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1002/anie.199406611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Within only five minutes at 20°C bimetallic fulvalene complexes 1 undergo intramolecular disproportionation in the presence of PMe3 or P(OMe)3 when electron‐reservoir complexes of the type [FeICp(arene)] serve as catalysts. MI = Mo, W, Fe, Ru; M2 = Mo, W; n = 2, 3; m = 3; arene = C6H6, C6Me6. The heterodinuclear complexes react with regioselectivity. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：661 / 663

页数：3

共 38 条

[1]

ASTRUC D, 1992, NEW J CHEM, V16, P305

[2] ORGANOIRON ELECTRON-RESERVOIR COMPLEXES [J].