DEFINITE EVIDENCE OF A PRIMARY PHOTOAQUATION REACTION OF OCTACYANOMOLYBDATE(4) COMPLEX ANION

被引：22

作者：

BALZANI, V

MANFRIN, MF

MOGGI, L

机构：

[1] Istituto Chimico “G. Ciamician” dell'Universitá, Laboratorio di Fotochimica e Radiazioni d'Alta Energia del CNR, Bologna

[2] Istituto Chimico dell'Universitá, Centro Nazionale di Chimica dei Composti di Coordinazione ed Elemento-Organici del CNR, Ferrara

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 01期

关键词：

D O I：

10.1021/ic50071a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photochemical behavior of Mo(CN)84- was studied in aqueous and buffered solutions using 365- mμ radiations. Spectrophotometric and pH measurements were used to establish the nature and the kinetics of the photoreaction. Definite evidence was obtained in favor of a primary photoaquation reaction, whose quantum yield was 0.8, independent of the complex concentration and the light intensity. A previously suggested mechanism, based on a primary photoreaction leading to the “supercomplex” Mo(CN)8(H2O)24-, is criticized. © 1969, American Chemical Society. All rights reserved.

引用

页码：47 / &

共 43 条

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