COMPLEXES OF TUNGSTEN(V) WHICH CONTAIN ALKOXIDE AS A LIGAND

被引：21

作者：

RILLEMA, DP

REAGAN, WJ

BRUBAKER, CH

机构：

[1] Department of Chemistry, Michigan State University, East Lansing, Michigan

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/ic50073a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solutions of WCl5 in alcohols have been investigated. The solutions were acidic with HCl, neutral, or basic with alkoxide ion. A number of tetrachlorodialkoxo- and pentachloroalkoxotungstates(V) were prepared and characterized and spectra and magnetic properties were determined. A yellow compound [(CH3)4N]2[W(OC2H5)Cl6] was isolated from ethanol solutions which had been saturated with HCl. The pentachloroalkoxotungstate(V) species decomposed by the elimination of alkyl chloride to give a mixture of solid materials which probably contain tetrachlorooxotungstate(V). © 1969, American Chemical Society. All rights reserved.

引用

页码：587 / &

共 23 条

[1] FAR-INFRARED SPECTRA (190-460 CM.-1) OF TETRAETHYL-AMMONIUM SALTS OF SOME COMPLEX CHLORIDES AND BROMIDES [J].

ADAMS, DM ;

GERRATT, J ;

DAVIDSON, JM ;

CHATT, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (APR) :2189-&

[2] HALIDE AND OXYHALIDE COMPLEXES OF MOLYBDENUM AND TUNGSTEN [J].

ALLEN, EA ;

WILLIAMS, RG ;

EDWARDS, DA ;

BRISDON, BJ ;

FOWLES, GWA .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (OCT) :4649-&

[3] INFRARED SPECTRA OF SOME METAL ALKOXIDES, TRIALKYLSILYLOXIDES, AND RELATED SILANOLS [J].

BARRACLOUGH, C ;

BRADLEY, DC ;

LEWIS, J ;

THOMAS, IM .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JUL) :2601-&

[4]

BRADLEY DC, 1950, J CHEM SOC, P3453

[5] MAGNETIC AND SPECTRAL STUDIES ON TUNGSTEN(V) CHLORIDE AND BROMIDE AND SEVERAL OXYHALIDE AND HALIDE COMPLEXES OF MOLYBDENUM(V) AND TUNGSTEN(V) [J].

BRISDEN, BJ ;

EDWARDS, DA ;

MACHIN, DJ ;

MURRAY, KS ;

WALTON, RA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (11) :1825-&

[6]

BRISDON BJ, 1965, J CHEM SOC, P2274

[7]

BRISDON BJ, 1964, J LESSCOMMON METALS, V7, P102

[8]

BRISDON BJ, 1965, J INORG NUCL CHEM, V27, P1101

[9] COMPLEX COMPOUNDS OF MOLYBDENUM AND TUNGSTEN PENTAHALIDES [J].

BROWN, TM ;

RUBLE, B .

INORGANIC CHEMISTRY, 1967, 6 (07) :1335-&

[10]

BUGNALL KW, 1964, J CHEM SOC, P2603

← 1 2 3 →