NOVEL ORGANOMETALLIC CHARGE-TRANSFER SALTS DERIVED FROM ELECTRON-RICH DIRUTHENIUM SPECIES AND THE ELECTRON-ACCEPTOR LIGANDS 7,7,8,8-TETRACYANO-PARA-QUINODIMETHANE AND TETRACYANOETHYLENE AND CONTAINING THE RADICAL-ANIONS OF THESE LIGANDS IN BOTH THE INNER AND THE OUTER COORDINATION SPHERES

被引：10

作者：

BELL, SE ^{[1
]}

FIELD, JS ^{[1
]}

HAINES, RJ ^{[1
]}

SUNDERMEYER, J ^{[1
]}

机构：

[1] UNIV NATAL,DEPT CHEM,METAL CLUSTER CHEM UNIT,POB 375,PIETERMARITZBURG 3200,SOUTH AFRICA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)83212-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the electron-rich diphosphazane-bridged diruthenium complexes [Ru2(mu-CO)(CO)4{mu-(RO)2PN(Et)P(OR)2}2] (R = Me or (i)Pr) with the electron-acceptor ligands 7,7,8,8-tetracyano-p-quinodimethane, TCNQ, and tetracyanoethylene, TCNE, results in electron transfer and the formation of the charge transfer salts [Ru2(CO)5(TCNX){mu-(RO)2PN(Et)P(OR)2}2]TCNX (X = Q or E) containing the radical anion of the electron-acceptor ligand in both the inner and the outer coordination spheres.

引用

页码：C1 / C5

页数：5

共 20 条

[1] BARTLEY SL, 1991, ANGEW CHEM, V103, P447
[2] METAMAGNETIC PROPERTIES OF ONE-DIMENSIONAL DECAMETHYLFERROCENIUM 7,7,8,8-TETRACYANO-P-QUINODIMETHANIDE (1-1)-[FE(ETA5-C5ME5)2]+.(TCNQ)-.
CANDELA, GA
SWARTZENDRUBER, LJ
MILLER, JS
RICE, MJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (10) : 2755 - 2756
[3] DEGREE OF CHARGE-TRANSFER IN ORGANIC CONDUCTORS BY INFRARED-ABSORPTION SPECTROSCOPY
CHAPPELL, JS
BLOCH, AN
BRYDEN, WA
MAXFIELD, M
POEHLER, TO
COWAN, DO
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) : 2442 - 2443
[4] ENGEL DW, 1987, J CHEM SOC CHEM COMM, P1457
[5] ELECTROCHEMICAL-BEHAVIOR OF DITERTIARY PHOSPHINE AND DIPHOSPHAZANE LIGAND-BRIDGED DERIVATIVES OF DI-IRON AND DI-RUTHENIUM NONACARBONYL
FIELD, JS
FRANCIS, AMA
HAINES, RJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (01) : C23 - C28
[6] SYNTHESIS OF THE SOLVENTO SPECIES [RU2(CO)5(SOLVENT)(MU-(RO)2PN(ET)P(OR)2)2]2+ AND ITS POTENTIAL AS A SOURCE FOR A WIDE-RANGE OF DINUCLEAR DERIVATIVES OF RUTHENIUM
FIELD, JS
HAINES, RJ
HONRATH, U
SUNDERMEYER, J
WOOLLAM, SF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (01) : C9 - C15
[7] READY DEPROTONATION OF THE PROTIC SOLVENTO SPECIES [RU2(CO)5(R'OH)(MU-(RO)2PN(ET)P(OR)2)2]2+ (R = ME OR PRI-R' = H, ME, ET, ETC) AND THE FORMATION OF [RU2(MU-OC(O))(CO)4(MU-(RO)2PN(ET)P(OR)2)2] CONTAINING CARBON-DIOXIDE IN A BRIDGING COORDINATION MODE
FIELD, JS
HAINES, RJ
SUNDERMEYER, J
WOOLLAM, SF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (14) : 985 - 988
[8] ELECTROCHEMICAL-BEHAVIOR OF DITERTIARY PHOSPHINE AND DIPHOSPHAZANE LIGAND-BRIDGED DERIVATIVES OF DIIRON AND DIRUTHENIUM NONACARBONYL
FIELD, JS
FRANCIS, AMA
HAINES, RJ
WOOLLAM, SF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) : 383 - 396
[9] ELECTROPHILIC ATTACK ON DIPHOSPHAZANE-BRIDGED DERIVATIVES OF DIRUTHENIUM NONACARBONYL BY HALOGENS - CRYSTAL-STRUCTURE OF [RU2(MU-I)I(CO)3(MU-(PRIO)2PN(ET)P(OPRI)2)2]
FIELD, JS
HAINES, RJ
MINSHALL, E
SAMPSON, CN
SUNDERMEYER, J
WOOLLAM, SF
ALLEN, CC
BOEYENS, JCA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (10): : 2761 - 2768
[10] ORGANOMETALLIC SOLID-STATE CHEMISTRY
GREEN, MLH
QIN, JG
OHARE, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 358 (1-3) : 375 - 388

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