SYNTHESIS AND NMR CHARACTERIZATION OF A BIS-STRAPPED 6-COORDINATE FE(II) CYTOCHROME-C MODEL

被引：7

作者：

BOITREL, B ^{[1
]}

LECASNAWROCKA, A ^{[1
]}

ROSE, E ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM ORGAN LAB,CNRS,TOUR 44-45,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 02期

关键词：

CYTOCHROME-C; PORPHYRIN; MODELIZATION; 6-COORDINATE FE(II);

D O I：

10.1016/0040-4039(92)88057-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new hexadentate bis-strapped porphyrin 6 has been synthesized with two different ansa, bringing in an intramolecular way, a nitrogen base and a thioether sixth ligand both necessary to mimic the natural cytochrome-C protein. H-1 NMR spectroscopy indicates clearly the six coordination of the iron atom.

引用

页码：227 / 230

页数：4

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