RUTHENIUM-CATALYZED OXIDATION OF ALCOHOLS BY ACETONE

被引：76

作者：

WANG, GZ ^{[1
]}

BACKVALL, JE ^{[1
]}

机构：

[1] UNIV UPPSALA,DEPT ORGAN CHEM,BOX 531,S-75121 UPPSALA,SWEDEN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000337

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Secondary alcohols are readily converted to ketones under mild conditions by acetone in the presence of a catalytic amount of RuCl2(PPh3)3; in some cases the reaction is co-catalysed by acetophenone.

引用

页码：337 / 339

页数：3

共 14 条

[1] RUTHENIUM-CATALYZED AEROBIC OXIDATION OF ALCOHOLS VIA MULTISTEP ELECTRON-TRANSFER
BACKVALL, JE
CHOWDHURY, RL
KARLSSON, U
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (07) : 473 - 475
[2] BENNETT MA, 1982, COMPREHENSIVE ORGANO, V4, P721
[3] DISPROPORTIONATION OF ACYCLIC KETONES TO CARBOXYLATE IONS AND ETHERS - A POISONING REACTION ON THE WAY TO THE CHEMOSELECTIVE REDUCTION OF ALPHA,BETA-UNSATURATED KETONES TO ALLYLIC ALCOHOLS VIA HYDROGEN-TRANSFER CATALYZED BY A NONCLASSICAL RUTHENIUM(II) TRIHYDRIDE
BIANCHINI, C
FARNETTI, E
FREDIANI, P
GRAZIANI, M
PERUZZINI, M
POLO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (19) : 1336 - 1337
[4] THE SELECTIVE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES BY O-2 EMPLOYING A TRINUCLEAR RUTHENIUM CARBOXYLATE CATALYST
BILGRIEN, C
DAVIS, S
DRAGO, RS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) : 3786 - 3787
[5] CHATT J, 1964, J CHEM SOC, V3, P3466
[6] EFFICIENT RUTHENIUM-CATALYZED TRANSFER HYDROGENATION OF KETONES BY PROPAN-2-OL
CHOWDHURY, RL
BACKVALL, JE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (16) : 1063 - 1064
[7] DICHLOROTETRAKIS(DIMETHYL SULPHOXIDE)RUTHENIUM(II) AND ITS USE AS A SOURCE MATERIAL FOR SOME NEW RUTHENIUM(II) COMPLEXES
EVANS, IP
SPENCER, A
WILKINSO.G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (02): : 204 - 209
[8] Furniss B.S., 1989, VOGELS TXB PRACTICAL, Vfifth
[9] HAINES AH, 1988, METHODS OXIDATION OR
[10] MULLER P, 1981, TETRAHEDRON LETT, P2361

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