PRECISE PARAMETER ESTIMATION IN REACTION MODELLING - SENSITIVITY IN CHOOSING EXPERIMENTAL CONDITIONS

被引:8
作者
MEZAKI, R
机构
[1] Engineering and Applied Science Department, Yale University, New Haven, Connecticut
关键词
D O I
10.1002/cjce.5450470217
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A sequential experimental design developed by Box and coworkers was reviewed and the sensitivity of experimental conditions in increasing the preciseness of parameter estimates was examined. Continuous kinetic data were utilized for the examination. It is found that experimental conditions are in some cases rather sinsitive and slightly deviated experimental conditions from those specified by the criterion may induce some difficulty in reducing the size of confidence region of parameter estimates. Copyright © 1969 Canadian Society for Chemical Engineering
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页码:192 / &
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