SYNTHESIS OF UNSUBSTITUTED AND 4,4'-SUBSTITUTED OLIGOBIPYRIDINES AS LIGAND STRANDS FOR HELICATE SELF-ASSEMBLY

被引：80

作者：

HARDING, MM ^{[1
]}

KOERT, U ^{[1
]}

LEHN, JM ^{[1
]}

MARQUISRIGAULT, A ^{[1
]}

PIGUET, C ^{[1
]}

SIEGEL, J ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,CHIM SUPRAMOLEC LAB,CNRS,URA 422,4 RUE BLAISE PASCAL,F-67070 STRASBOURG,FRANCE

来源：

HELVETICA CHIMICA ACTA | 1991年 / 74卷 / 03期

关键词：

D O I：

10.1002/hlca.19910740317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general strategy for the synthesis of oligobipyridine ligands 2-5 containing from two to five 2,2'-bipyridine subunits, for helical metal complexes is described (see Scheme). Both the unsubstituted parent strands (a series) as well as their derivatives bearing ester or amide functions in the 4,4'-positions of the bipyridine moieties (b-d series) have been obtained.

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页码：594 / 610

页数：17

相关论文

共 17 条

[1] REARRANGEMENTS OF N-OXIDES - A NOVEL SYNTHESIS OF PYRIDYL CARBINOLS AND ALDEHYDES [J].

BOEKELHEIDE, V ;

LINN, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (05) :1286-1291

[2] SELF-ASSEMBLY OF SILVER(I) HELICATES [J].

GARRETT, TM ;

KOERT, U ;

LEHN, JM ;

RIGAULT, A ;

MEYER, D ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (07) :557-558

[3]

HE Y, 1990, CHEM J CHINESE U, V6, P183

[4]

HE Y, UNPUB

[5] PROTOPHANES AND POLYAROMATICS .22. NUCLEOPHILIC ALKYLATION AND ARYLATION OF 2,2'-BIPYRDYL [J].

KAUFFMANN, T ;

KONIG, J ;

WOLTERMANN, A .

CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (12) :3864-3868

[6] DNH DEOXYRIBONUCLEOHELICATES - SELF ASSEMBLY OF OLIGONUCLEOSIDIC DOUBLE-HELICAL METAL-COMPLEXES [J].

KOERT, U ;

HARDING, MM ;

LEHN, JM .

NATURE, 1990, 346 (6282) :339-342

[7]

Lehn J., 1990, ANGEW CHEM, V102, P1347, DOI DOI 10.1002/ANGE.19901021117

[8] SPONTANEOUS ASSEMBLY OF DOUBLE-STRANDED HELICATES FROM OLIGOBIPYRIDINE LIGANDS AND COPPER(I) CATIONS - STRUCTURE OF AN INORGANIC DOUBLE HELIX [J].

LEHN, JM ;

RIGAULT, A ;

SIEGEL, J ;

HARROWFIELD, J ;

CHEVRIER, B ;

MORAS, D .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1987, 84 (09) :2565-2569

[9] PERSPECTIVES IN SUPRAMOLECULAR CHEMISTRY - FROM MOLECULAR RECOGNITION TOWARDS MOLECULAR INFORMATION-PROCESSING AND SELF-ORGANIZATION [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (11) :1304-1319

[10] EFFICIENT SYNTHESIS OF 1,2-BIS(2,2'-BIPYRIDINYL)ETHANE AND 1,2-BIS(1,10-PHENANTHROLINYL)ETHANE LIGANDS BY OXIDATIVE COUPLING OF THE CORRESPONDING MONOMERIC METHYLENE CARBANIONS [J].

LEHN, JM ;

ZIESSEL, R .

HELVETICA CHIMICA ACTA, 1988, 71 (06) :1511-1516