HETP OF AN UNRETAINED COMPONENT OF FLUID-FLOW IN A COILED ROUND PIPE

被引:21
作者
GOLAY, MJE
机构
[1] The Perkin-Elmer Corporation, Norwalk
来源
JOURNAL OF CHROMATOGRAPHY | 1979年 / 186卷 / DEC期
关键词
D O I
10.1016/S0021-9673(00)95260-9
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
When poiseuille flow occurs in an open-tubular curved pipe, the secondary currents created by centrifugal forces within the primary current cause a lowering of the HETP of the primary current for samples carried along. An expression is developed for th e first approximation of this effect,which is represented by a term proportional to the fourth power of the primary flow. The calculations are made for the less involved case of a circular pipe with retentionless walls, and serve to show that, while measurable effects can be expected for relatively high flow-rates, the effect is negligible in the case of the relatively slow flows of liquids at which optimal chromatographic separations are obtained. © 1979.
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页码:341 / 351
页数:11
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