A DIRECT METHOD FOR THE DERIVATION OF THERMODYNAMIC EXCESS FUNCTIONS FROM TX PHASE-DIAGRAMS .2. IMPROVED METHOD APPLIED TO EXPERIMENTAL REGIONS OF DEMIXING

被引：17

作者：

BROUWER, N ^{[1
]}

OONK, HAJ ^{[1
]}

机构：

[1] STATE UNIV UTRECHT,GEN CHEM LAB,CHEM THERMODYNAM GRP,UTRECHT,NETHERLANDS

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-WIESBADEN | 1979年 / 117卷

关键词：

Excess enthalpy; Excess entropy; Least-squares refinement; Regions of demixing;

D O I：

10.1524/zpch.1979.117.117.055

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The direct method, which was described in part I, and which permits the simultaneous derivation of the HE and SE functions from one single TX phase diagram has been improved. The improved method is applied to experimental regions of demixing. The significance of the results is investigated by recalculation of the regions of demixing and also by comparison with experimental heats of mixing. © 1979, Akademische Verlagsgesellschaft.

引用

页码：55 / 67

页数：13

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