PYRAZINE-FUSED BIS(TETRATHIAFULVALENES)

被引：16

作者：

LAHLIL, K

MORADPOUR, A

MERIENNE, C

BOWLAS, C

机构：

[1] UNIV PARIS 11,PHYS SOLIDES LAB,CNRS,UA 2,F-91405 ORSAY,FRANCE

[2] UNIV PARIS 11,CHIM & PHYS CHIM MILIEUX STRUCT LAB,CNRS,UA 1384,F-91405 ORSAY,FRANCE

[3] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 26期

关键词：

D O I：

10.1021/jo00105a018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

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页码：8030 / 8033

页数：4

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