CHARGED GUEST RECOGNITION BY REDOX RESPONSIVE LIGAND SYSTEMS

被引:44
作者
BEER, PD
机构
[1] Inorganic Chemistry Laboratory, University of Oxford, Oxford, OX1 3QR, South Parks Road
关键词
D O I
10.1002/adma.19940060721
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Redox responsive macrocyclic ligands can be used for the recognition of charged guest molecules and so are of importance for potential new molecular sensory devices. Systems are reported that enable the electrochemical recognition of various cations and anions. Tripodal cobalticinium and ferrocene ionophores electrochemically recognize H2PO4- in the presence of excess HSO4- and Cl- anions.
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页码:607 / 609
页数:3
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