STUDY OF THE REACTION OF A CHIRAL OXAZOLONE WITH OXOSULFONIUM METHYLIDES AS CYCLOPROPANATING AGENTS

被引:17
作者
CATIVIELA, C
DIAZDEVILLEGAS, MD
JIMENEZ, AI
机构
[1] Departamento de Química Orgánica. Instituto de Ciencia de Materiales, Aragón. Universidad de Zaragoza-C.S.I.C.
关键词
D O I
10.1016/0040-4020(95)00033-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The behaviour of the chiral Z-oxazolone derived from 1,2-O-isopropylidene-D-glyceraldehyde towards oxosulphonium methylides as cyclopropanating agents has been studied. The solvent and temperature dependence of the ratio of the products is described
引用
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页码:3025 / 3032
页数:8
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