MOLECULAR ALUMINUM TRIHYDRIDE, ALH3 - GENERATION IN A SOLID NOBLE-GAS MATRIX AND CHARACTERIZATION BY ITS INFRARED-SPECTRUM AND AB-INITIO CALCULATIONS

被引:66
作者
KURTH, FA
EBERLEIN, RA
SCHNOCKEL, H
DOWNS, AJ
PULHAM, CR
机构
[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY
[2] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND
[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1039/c39930001302
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Broad-band photolysis of a solid noble gas matrix containing Al atoms and H-2 gives rise to the planar, monomeric AlH3 molecule, isotopically natural and deuteriated forms of which have been characterised by their IR spectra; confirmation is afforded by the results of MP2 ab initio and normal coordinate analysis calculations.
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收藏
页码:1302 / 1304
页数:3
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