SYNTHESIS AND MOLECULAR-STRUCTURE OF ALME[O=C(OME)C6H4-O-O]2 - THE 1ST STRUCTURALLY CHARACTERIZED 5-COORDINATED SIMPLE ALKYLALUMINUM CHELATE COMPLEX

被引：31

作者：

LEWINSKI, J

ZACHARA, J

MANK, B

PASYNKIEWICZ, S

机构：

[1] Department of Chemistry, Warsaw Technical University, 00-662 Warsaw

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83216-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of AlMe3 with 2 equiv. of O=C(OMe)C6H4-o-OH leads to the formation of the mononuclear, five-coordinated aluminium compound AlMe[O=C(OMe)C6H4-o-0]2. The title compound has been characterized by IR, H-1 and Al-27 NMR spectroscopies and its structure has been confirmed by X-ray crystallography. The compound crystallizes in the monoclinic space group C2/c with the unit cell parameters a = 16.144(2), b = 7.703(1), c = 14.792(2) angstrom, beta = 112.76(l)-degrees, Z = 4, observed data = 1060, R = 0.0380, R(w) = 0.0378.

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页码：5 / 7

页数：3

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