THE STRUCTURE OF HEXA(CYCLOHEXYLSESQUISILOXANE), (C6H11)6SI6O9

被引：21

作者：

BEHBEHANI, H ^{[1
]}

BRISDON, BJ ^{[1
]}

MAHON, MF ^{[1
]}

MOLLOY, KC ^{[1
]}

机构：

[1] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 469卷 / 01期

关键词：

SILICON; SILOXANE; SESQUISILOXANE; STRUCTURE; X-RAY DIFFRACTION; CAGE COMPOUND;

D O I：

10.1016/0022-328X(94)80073-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of hexa(cyclohexylsesquisiloxane), Cy6Si6O9, has been determined and shown to be based on a cage arrangement in which two non-planar six-membered Si3O3 rings are joined co-facially by Si-O-Si bridges, so generating three further Si4O4 rings. The structural variations in six- and eight-membered (Si-O)(n) rings in this and other known cage sesquisiloxanes are analysed and compared with those of analogous rings in two-dimensional diorganosiloxane heterocycles.

引用

页码：19 / 23

页数：5

共 30 条

[1] A NEW ROUTE TO TRIMETHYLSILYLATED SPHEROSILICATES - SYNTHESIS AND STRUCTURE OF [SI12O18](OSIME3)12, D3H-[SI14O21](OSIME3)14, AND C2V-[SI14O21](OSIME3)14
AGASKAR, PA
DAY, VW
KLEMPERER, WG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (18) : 5554 - 5556
[2] ORGANOLITHIC MACROMOLECULAR MATERIALS DERIVED FROM VINYL-FUNCTIONALIZED SPHEROSILICATES - NOVEL POTENTIALLY MICROPOROUS SOLIDS
AGASKAR, PA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) : 6858 - 6859
[3] BAIDINA IA, 1980, ZH STRUKT KHIM, V21, P125
[4] ATR-FTIR EXPERIMENTS WITH R8[SI8O12] ON GE AND ZNSE
BEER, R
BURGY, H
CALZAFERRI, G
KAMBER, I
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1987, 44 : 121 - 130
[5] THE STRUCTURE OF 1,1,3,3,5,5-HEXAPHENYL-1,3-5-TRISILOXANE-1,5-DIOL
BEHBEHANI, H
BRISDON, BJ
MAHON, MF
MOLLOY, KC
MAZHAR, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 463 (1-2) : 41 - 45
[6] THE ROOM-TEMPERATURE STRUCTURE OF OCTAPHENYLCYCLOTETRA(SILOXANE) (OPCTS)
BRAGA, D
ZANOTTI, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (APR): : 950 - 953
[7] FORMATION OF Q8M10([(CH3)3SIO]10SI8O11) FROM QM4([(CH3)3SIO]4SI), OLIVINE AND DIOPTASE
BRATTON, GJ
CURRELL, BR
PARSONAGE, JR
WALL, GK
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (06) : 943 - 946
[8] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF CYCLOBORASILOXANES - THE X-RAY CRYSTAL-STRUCTURES OF CYCLO-1,3,3,5,5-PENTAPHENYL-1-BORA-3,5-DISILOXANE AND CYCLO-1,3,3,5,7,7-HEXAPHENYL-1,5-DIBORA-3,7-DISILOXANE
BRISDON, BJ
MAHON, MF
MOLLOY, KC
SCHOFIELD, PJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 436 (01) : 11 - 22
[9] PREPARATION + CHARACTERIZATION OF LOWER EQUILIBRATED PHENYLSILSESQUIOXANES
BROWN, JF
VOGT, LH
PRESCOTT, PI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (06) : 1120 - &
[10] THE SYMMETRICAL OCTASILASESQUIOXANES X8SI8O12 - ELECTRONIC-STRUCTURE AND REACTIVITY
CALZAFERRI, G
HOFFMANN, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, : 917 - 928

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