PHOTOLYTIC SEPARATION OF CARBON ISOTOPES IN CRYOGENIC SOLUTIONS OF CARBON-DISULFIDE

被引：6

作者：

FREUND, SM ^{[1
]}

MAIER, WB ^{[1
]}

HOLLAND, RF ^{[1
]}

BEATTIE, WH ^{[1
]}

机构：

[1] UNIV CALIF LOS ALAMOS SCI LAB,LOS ALAMOS,NM 87545

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 16期

关键词：

D O I：

10.1021/ja00510a016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the separation of carbon isotopes by photolysis of CS2 in cryogenic solutions of nitrogen, krypton, and argon with 206-nm light from an iodine resonance lamp. The spectral distribution of the ultraviolet absorption depends on solvent. Thus, in liquid nitrogen the photolytic rate of13CS2 is greater than that of 12CS2, whereas in liquid krypton and liquid argon the reverse is true. © 1979, American Chemical Society. All rights reserved.

引用

页码：4522 / 4524

页数：3

共 14 条

[1] REACTIONS OF SULPHUR ATOMS IN PRESENCE OF CARBON DISULPHIDE CARBONYL SULPHIDE AND NITRIC OXIDE [J].

BASCO, N ;

PEARSON, AE .

TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (539P) :2684-&

[2]

DEPOORTER GL, 1977, INORG NUCL CHEM LETT, V13, P459

[3]

ENGLEMAN R, 1971, GMX2 LASL OFF MEM

[4]

Freund S. M., 1978, Analytical Chemistry, V50, P1260, DOI 10.1021/ac50031a017

[5]

FREUND SM, UNPUBLISHED

[6]

HARTECK P, 1964, Z NATURFORSCH PT A, VA 19, P2

[7]

Herzberg G., 1966, MOL SPECTRA MOL STRU, VIII

[8]

LOREE T, UNPUBLISHED

[9] PHOTOLYTIC SEPARATION OF D FROM H IN CRYOGENIC SOLUTIONS OF FORMALDEHYDE [J].

MAIER, WB ;

FREUND, SM ;

HOLLAND, RF ;

BEATTIE, WH .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (05) :1961-1965

[10]

RABALAIS JW, 1971, CHEM REV, V71, P73

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