INVERSE PHASE-TRANSFER CATALYSIS BY CYCLODEXTRINS - PALLADIUM-CATALYZED REDUCTION OF BROMOANISOLES WITH SODIUM FORMATE

被引：24

作者：

SHIMIZU, S

SASAKI, Y

HIRAI, C

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.176

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bromoanisoles have been reduced to hydrocarbons with sodium formate in high yields under mild conditions using palladium on charcoal and cyclodextrins as catalysts. In aqueous phase-organic phase reactions employing a solid-phase catalyst (Pd/C), cyclodextrins function as inverse phase-transfer catalysts which transfer the substrate into the aqueous phase.

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页码：176 / 178

页数：3

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