PRELIMINARY RAMAN MICROSCOPIC ANALYSES OF A LICHEN ENCRUSTATION INVOLVED IN THE BIODETERIORATION OF RENAISSANCE FRESCOES IN CENTRAL ITALY

被引：48

作者：

EDWARDS, HGM

FARWELL, DW

SEAWARD, MRD

GIACOBINI, C

机构：

[1] Department of Environmental Science, University of Bradford, Bradford

[2] Istituto Centrale del Restauro, 00184 Roma

来源：

INTERNATIONAL BIODETERIORATION | 1991年 / 27卷 / 01期

关键词：

D O I：

10.1016/0265-3036(91)90019-N

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Raman microscopic analysis has proved effective in the interpretation and characterization of both the physical and chemical nature of the lichen/substratum system. In the case of Dirina massiliensis forma sorediata, a lichen causing extensive damage to Italian frescoes, the lichen-generated encrustation has been proved to be composed essentially of calcium oxalate. This particular biodeterioration process may be slowed down, or indeed inhibited, by the presence of certain compounds, as yet undetermined, used in the preparation of surfaces and the painting of frescoes. From a conservator's point of view. Raman microscopic analysis uses microscopic samples in the nanogram-picogram range and is non-destructive of the sample.

引用

页码：1 / 9

页数：9

共 14 条

[1]

Ascaso, Galvan, Rodriguez-Pascual, The weathering of calcareous rocks by lichens, Pedobiologia, 24, pp. 219-229, (1982)

[2]

Ballan-Dufrancais, Truchet, Dhamelincourt, Intérêt de la microsonde à l'effet Raman (MOLE) pour l'identificationnde concretions publiques sur coupes histologiques, Proc. 7th Conf. on Raman Spectroscopy, pp. 566-567, (1980)

[3]

Barbillat, DeleDubois, Delhaye, Dhamelincourt, Laweyns, Intérêt de la microsonde a l'effet Raman (MOLE) dans le domaine de la géologie, Proc. 7th Conf. on Raman Spectroscopy, pp. 138-139, (1980)

[4]

Delhaye, Dhamelincourt, Raman microprobe and microscope with laser excitation, Journal of Raman Spectroscopy, 3, pp. 33-43, (1975)

[5]

Jones, Wilson, International Biodeterioration, Chemical activity of lichens on mineral surfaces — a review, 21, pp. 99-104, (1985)

[6]

Jones, Wilson, Tait, Weathering of a basalt by Pertusaria corallina, Lichenologist, 12, pp. 277-289, (1980)

[7]

Purvis, The occurrence of copper oxalate in lichens growing on copper sulphide-bearing rocks in Scandinavia, Lichenologist, 16, pp. 197-204, (1984)

[8]

Seaward, Giacobini, Oxalate encrustation by the lichen Dirina massiliensis forma sorediata and its role in the deterioration of works of art, Le pellicole ad ossalati. Origine e significato nella conservazione delle opere d'arte, pp. 215-219, (1989)

[9]

Seaward, Giacobini, Lichen-induced biodeterioration of Italian monuments, frescoes and other archaeological materials, Studia Geobotanica, 9, (1990)

[10]

Vidrich, Cecconi, Ristori, Fusi, Verwittering toskanischer Gesteine unter Mitwirkung von Flechten, Zeitschrift für Pflanzenernährung und Bodenkunde, 145, pp. 384-389, (1982)

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