SPECTROSCOPIC ASSESSMENT OF THE DEGREE OF PI-STABILIZATION OF UNSATURATION IN RUH(X)CO(PTBU2ME)2

被引：126

作者：

POULTON, JT ^{[1
]}

FOLTING, K ^{[1
]}

STREIB, WE ^{[1
]}

CAULTON, KG ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 15期

关键词：

D O I：

10.1021/ic00041a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The question of ligand (X)-to-metal pi-donation is addressed in compounds of the type RuH(CO)X(PtBu2Me)2. Using the C/O stretching frequency as a probe of relative total (sigma + pi)-donor ability, it is possible to establish the ranking OSiMe3 > OSiMe2- Ph > OSiPh3 > OCH2CF3 > OH > NHPh > OPh > Cl > I.

引用

页码：3190 / 3191

页数：2

共 6 条

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