MONONUCLEAR ARYLAMIDO COMPLEXES OF IRIDIUM(I)

被引：33

作者：

RAHIM, M

WHITE, C

RHEINGOLD, AL

AHMED, KJ

机构：

[1] UNIV VERMONT,DEPT CHEM,BURLINGTON,VT 05405

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 07期

关键词：

D O I：

10.1021/om00031a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and the first structural characterization of arylamido complexes of Ir(I), having the general formula trans-Ir(CO)(NHAr)(PPh3)2, where Ar = Ph (1), p-C6H4Me (2), 2,6-C6H3Me2 (3), are described. Preliminary results of their facile insertion reactions with CO and CO2 are also discussed.

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页码：2401 / 2403

页数：3

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