SYNTHESIS, CHARACTERIZATION, AND PRESSURE-DEPENDENCE OF CONDUCTIVITY FOR A PARTIALLY OXIDIZED TETRA-AZA MACROCYCLIC PALLADIUM COMPLEX

被引：15

作者：

MERTES, KB ^{[1
]}

FERRARO, JR ^{[1
]}

机构：

[1] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 02期

关键词：

D O I：

10.1063/1.437492

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and characterization of the I2 oxidation product of a tetra-aza macrocyclic complex of Pd (II) is described. The product is formulated as [Pd (TAAB)] [I3]2.7 where TAAB is tetrabenzo [b, f, j, n] [1, 5, 9, 13] tetra-azacyclohexadecine. The presence of I3 was confirmed by Raman and far-infrared spectroscopy. Electrical conductivity measurements for pressed powder samples using a diamond-anvil pressure cell showed an unusually large pressure dependence. © 1979 American Institute of Physics.

引用

页码：646 / 648

页数：3

共 26 条

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