A NEW ROUTE TO OLEFIN COMPLEXES OF COPPER(I) COMPOUNDS

被引：57

作者：

COOK, BW

MILLER, RGJ

TODD, PF

机构：

[1] Imperial Chemical Industries Limited, Petrochemical and Polymer Laboratory, The Heath. Runcorn,, Cheshire Cheshire

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 19卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)85316-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of olefin complexes of Cu1 compounds by the following reaction is described:. CuX2 + olefin + (RO)3P→[olefinx(CuX)y]n + (R′O)3P = O where X = Cl,Br,ClO4 or BF4, R = alkyl or phenyl, R′ = H, alkyl or aryl not necessarily the same as R, x, y = 1 or 2, n = unknown. The IR spectra of these complexes have been studied, and are discussed in relation to the structure of the compounds. © 1969.

引用

页码：421 / &

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