METALLOCENYL CARBONIUM IONS . PARTICIPATION BY FERROCENE IN SOLVOLYSIS OF BETA-FERROCENYLALKYL TOSYLATES

被引：36

作者：

NUGENT, MJ

CARTER, RE

RICHARDS, JH

机构：

[1] Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena

[2] Academy for Chemistry, Nobel Institute

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 22期

关键词：

D O I：

10.1021/ja01050a038

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The participation of the ferrocenyl group during solvolysis of β-ferrocenylalkyl tosylates has been demonstrated by (a) the entropy of activation, (b) the difference in solvolysis rate in acetic acid and 80% aqueous acetone, (c) the effect of methyl substitution on the α-carbon, (d) the kinetic isotope effect in the solvolysis of 1,1-dideuterio-2-ferrocenylethyl tosylate, and (e) the complete retention of configuration in the solvolysis of optically active l-ferrocenyl-2-propyl tosylate. © 1969, American Chemical Society. All rights reserved.

引用

页码：6145 / &

共 37 条

[1]

BELLAMY LJ, 1958, INFRARED SPECTRA COM, P34

[2]

BELLAMY LJ, 1958, INFRARED SPECTRA COM, P13

[3]

BERGER H, 1961, J AM CHEM SOC, V83, P2274

[4] THE RELATIVE REACTION VELOCITIES OF ISOTOPIC MOLECULES [J].