COBALT(II) TETRAPHENYLPORPHYRIN PYRIDINE COMPLEX FIXED ON A GLASSY-CARBON ELECTRODE AND ITS PROMINENT CATALYTIC ACTIVITY FOR REDUCTION OF CARBON-DIOXIDE

被引：73

作者：

ATOGUCHI, T

ARAMATA, A

KAZUSAKA, A

ENYO, M

机构：

[1] HOKKAIDO UNIV,CATALYSIS RES CTR,SAPPORO,HOKKAIDO 060,JAPAN

[2] HOKKAIDO UNIV,FAC VET MED,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cobalt(II)-tetraphenylporphyrin (Co(II)tpp)-fixed glassy carbon (GC) electrodes were prepared using 4-aminopyridine (pyNH2) in the form of CoIItpp-pyNH-CO/GC, which were active for electroreduction of CO2 to CO at potentials 100 mV more positive than water-soluble Co(II) porphyrins, and the overall turnover number of Co(II)tpp for CO production exceeded 10(5).

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页码：156 / 157

页数：2

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