CORRELATION BETWEEN OXYGEN-UPTAKE AND CARBONYL FORMATION IN POLYETHYLENE OXIDATION

被引:14
作者
FODOR, Z [1 ]
IRING, M [1 ]
TUDOS, F [1 ]
机构
[1] EOTVOS LORAND UNIV, DEPT CHEM TECHNOL, H-1364 BUDAPEST 5, HUNGARY
来源
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1991年 / A28卷 / 07期
关键词
D O I
10.1080/00222339108052115
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The ratio of absorbed O2 and carboxyl groups formed was studied in LDPE oxidation. It was found that this ratio is independent of the reaction conditions in a wide range (20-100 kPa O2 pressure, 90-160-degrees-C, and thickness of 20-1170-mu-m). If the pressure of O2 was 2.7 kPa, less -COOH formed. A semiempirical mathematic equation was constructed to describe the relation between the acid content and oxygen consumption.
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页码:641 / 650
页数:10
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