DIASTEREOFACIAL SELECTIVITY IN INTERMOLECULAR NITRONE CYCLOADDITIONS TO CHIRAL ALLYL ETHERS - APPLICATION TO CHIRAL SYNTHESIS OF CONIINE

被引：44

作者：

ITO, M ^{[1
]}

MAEDA, M ^{[1
]}

KIBAYASHI, C ^{[1
]}

机构：

[1] TOKYO COLL PHARM,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 26期

关键词：

D O I：

10.1016/0040-4039(92)80019-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intermolecular cycloadditions of a cyclic nitrone to chiral allyl ethers take place with erythro selectivity, where the degree of selectivity achieved is dependent upon the size of the alkyl substituent attached to the allylic chiral center, and these reactions are applied to the synthesis of optically active alkaloid coniine.

引用

页码：3765 / 3768

页数：4

共 20 条

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