STRUCTURE AND REACTIVITY OF N-METHYLPYRID-2-ONE, N-METHYLPYRID-2-ONE METHIDE AND THEIR BENZO HOMOLOGS

被引：11

作者：

SEIFFERT, W

MANTSCH, HH

机构：

[1] National Research Council of Canada, Pure Chemistry Division

来源：

TETRAHEDRON | 1969年 / 25卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)82999-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The π-electronic structure of compounds I-IV has been calculated by a β-variable SCF-method within the general PPP-framework and the corresponding molecular diagrams were computed. By considering the chemical reactivity of III and IV, the approach of a hypothetical positive particle towards the reacting molecule was simulated by calculations, which showed that the direction it approaches the reactive centre is controlled by steric factors. © 1969.

引用

页码：4569 / &

共 13 条

[1]

BARNES RA, 1960, PYRIDINE ITS DERIV 1, P68

[2] ADDITIONSREAKTIONEN ZWISCHEN FARBSTOFFKATIONEN (ELEKTRONENAKZEPTOREN) UND O-, N- UND C-LEWIS-BASEN (ELEKTRONENDONATOREN) ALS URSACHE FUR ANOMAL NIEDRIGE ABSORPTIONSBANDEN VON FARBSTOFFEN IN BESTIMMTEN LOSUNGSMITTELN [J].

BUTTGEREIT, G ;

SCHEIBE, G .

BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1965, 69 (04) :301-+

[3]

KLUGE W, 1968, THESIS TH MUNCHEN

[4]

MANTSCH HH, 1969, REV ROUM CHIM, V14, P125

[5]

Mataga N., 1957, Z PHYS CHEM, V13, P140, DOI [10.1524/zpch.1957.13.3_4.140, DOI 10.1524/ZPCH.1957.13.3_4.140]

[6] ELECTRON INTERACTION IN MOLECULES .2. PI-ELECTRONIC STRUCTURE OF SOME AROMATIC HYDROCARBONS AND THEIR DERIVATIVES [J].

NISHIMOTO, K .

THEORETICA CHIMICA ACTA, 1967, 7 (03) :207-+

[7] CLASSIFICATION OF SPECTRA OF CATA-CONDENSED HYDROCARBONS [J].

PLATT, JR .

JOURNAL OF CHEMICAL PHYSICS, 1949, 17 (05) :484-495

[8]

SCHEIBE G, 1966, TETRAHEDRON LETT, P5053

[9] ULTRAVIOLET SPECTROSCOPY OF MONOHYDROXYACRIDINES [J].

SEIFFERT, W ;

ZANKER, V ;

MANTSCH, H .

TETRAHEDRON, 1969, 25 (05) :1001-&

[10]

SEIFFERT W, 1968, TETRAHEDRON LETT, P3437

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