NEW METHOD FOR PREPARING ARSINIDENE COMPLEXES FROM DIMETALLA-ARSACUMULENIUM IONS

被引：20

作者：

STRUBE, A ^{[1
]}

HUTTNER, G ^{[1
]}

ZSOLNAI, L ^{[1
]}

IMHOF, W ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 399卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85492-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimetallaarsacumuleniumion [Cp'(CO)2Mn = As = Mn(CO)2Cp']+, 2, which is easily obtained by halide abstraction from the arsinidene complex Cp'(CO)2Mn-As-(Cl)-Mn(CO)2Cp', 1a, reacts with nucleophiles X- to give the arsinidene species Cp'(CO)2Mn-As(X)-Mn(CO)2Cp', 1c-1f (1c: X = 1, 1d: X = NCO, 1e: X = NCS, 1f: X = N3); with BH4- as the nucleophile the parent compound Cp'(CO)2Mn-As(H)-Mn(CO)2Cp', 1b, is obtained. The new arsinidene compounds 1b-1f are characterized by the standard analytic and spectroscopic techniques; in addition X-ray analyses are reported for 1b, 1c and 1e.

引用

页码：281 / 290

页数：10

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