SEQUENTIAL BIOCATALYTIC KINETIC RESOLUTIONS

被引：90

作者：

GUO, ZW ^{[1
]}

WU, SH ^{[1
]}

CHEN, CS ^{[1
]}

GIRDAUKAS, G ^{[1
]}

SIH, CJ ^{[1
]}

机构：

[1] UNIV WISCONSIN, SCH PHARM, MADISON, WI 53706 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 12期

关键词：

D O I：

10.1021/ja00168a046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quantitative expressions that govern sequential kinetic resolutions have been developed for calculation of the relative kinetic constants to allow optimization of chemical and optical yields. Enantiomerically pure (2R,4R)- and (2S,4S)-2,4-pentanediols have been prepared by biocatalyzed sequential enantioselective esterification in anhydrous isooctane. © 1990, American Chemical Society. All rights reserved.

引用

页码：4942 / 4945

页数：4

共 19 条

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