DYNAMICS OF MOLECULAR PHOTODISSOCIATION IN CLUSTERS - A STUDY OF AR-HCL

被引：52

作者：

GARCIAVELA, A

GERBER, RB

VALENTINI, JJ

机构：

[1] HEBREW UNIV JERUSALEM,FRITZ HABER RES CTR MOLEC DYNAM,IL-91904 JERUSALEM,ISRAEL

[2] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717

[3] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

[4] UNIV COMPLUTENSE MADRID,CSTC,CTR MIXTO,INST FIS FUNDAMENTAL,E-28006 MADRID,SPAIN

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 186卷 / 2-3期

关键词：

D O I：

10.1016/S0009-2614(91)85133-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photodissociation of HCl in the Ar-HCl cluster has been studied theoretically using a classical trajectory method to explore the effect of a "solvent" atom on the process. The calculated kinetic energy and angular distributions of the photofragments show a "cage" effect, due to collisions between H and the heavy atoms before H leaves the cluster. Also, significant differences are seen depending on whether a classical or a quasiclassical distribution is used to describe the initial Ar-HCl bending distribution.

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页码：223 / 228

页数：6

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